US2805944A - Lead alloy for bonding metals to ceramics - Google Patents

Lead alloy for bonding metals to ceramics Download PDF

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US2805944A
US2805944A US380533A US38053353A US2805944A US 2805944 A US2805944 A US 2805944A US 380533 A US380533 A US 380533A US 38053353 A US38053353 A US 38053353A US 2805944 A US2805944 A US 2805944A
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alloy
copper
lead
ceramics
titanium
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Bender Harry
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GTE Sylvania Inc
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
    • C04B37/026Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of metals or metal salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/26Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
    • B23K35/268Pb as the principal constituent
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/003Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts
    • C04B37/006Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts consisting of metals or metal salts
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C11/00Alloys based on lead
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658Atmosphere during thermal treatment
    • C04B2235/6581Total pressure below 1 atmosphere, e.g. vacuum
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12Metallic interlayers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12Metallic interlayers
    • C04B2237/126Metallic interlayers wherein the active component for bonding is not the largest fraction of the interlayer
    • C04B2237/127The active component for bonding being a refractory metal
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32Ceramic
    • CCHEMISTRY; METALLURGY
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40Metallic
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/52Pre-treatment of the joining surfaces, e.g. cleaning, machining
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/76Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc
    • C04B2237/765Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc at least one member being a tube
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/80Joining the largest surface of one substrate with a smaller surface of the other substrate, e.g. butt joining or forming a T-joint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/88Joining of two substrates, where a substantial part of the joining material is present outside of the joint, leading to an outside joining of the joint
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S228/00Metal fusion bonding
    • Y10S228/903Metal to nonmetal

Definitions

  • Figure 1 is a perspective view showing two ceramic bodies bonded together with the aid of a metal bond.
  • Figure 2 of the drawings is a perspective view of a .etal tube which has been metallized on one end thereof the metal extending a considerable distance up along the outside side wall.
  • Figure 3 is a plan view partially in section showing the alloy of this invention embedded within the pores of a screen-like material.
  • the alloy which has been found to be suitable for making the metal-to-ceramic seals in accordance with this invention is one which has preferably at least three component elements.
  • the base metal is lead. Titanium or zirconium form the second component and it is present in an amount not less than 0.1%, and copper the third component is present in tin-amount not less than 0.5 With this alloy it is possible to make a good ceramic-tometal or ceramic-to-ceramic seal bonded with a metallic bond. This can be done in a single step operation and 2.8%,944 Patented Sept. 10, 1957 glass to metal or ceramic.
  • the alloy which is formed from the mixture of the three components is fairly ductile in nature and can be formed into bars, sheets, wire and numerous other shapes which might be deemed to be useful and adaptable in the making of the seal.
  • a bond or seal can be made in a very simple manner, by taking the parts which are to be bonded together, subjecting them to a simple cleaning operation to remove any foreign materials which may be on the surface, placing them together, for example, to form a butt joint with a piece of the alloy material positioned therebetween, for example, in the form of a washer, and then heating them in a non-oxiding atmosphere.
  • the parts should be heated to'a temperature of 700-800 C. for a period of about three minutes.
  • the parts have been cooled it will be found that they have been joined in a vacuum tight manner and that the metal is tightly bonded to the ceramic and cannot be peeled or cut away from the ceramic body.
  • Figure 1 of the drawings shows two 'of ceramic parts which have been bonded together in'this manner.
  • 10 is a tubular piece of ceramic which has been bonded to a disc-like wafer 12 by means of the alloy 14.
  • FIG 2 is shown a tubular member 20 which has been metallized at one end 22 with the use of the alloy to form the metallized surface at 24.
  • the wettability of this alloy is so good, in certain instances, when the preferred composition is made use of that there is a tendency for the alloy to run at the bond and in order to hold the alloy in place so that the metal will actually cover the areas which it is intended to mctallize it has been found that a special structure may be desirable.
  • a structure of this type is shown in Figure 3 wherein the alloy is embedded within the pores of a screen-like material 30. There one can see the metallic parts 32 surrounding the screen-like material embedded within the interstices of the screen-like member.
  • the member 30 is, of course, made of a metal or other material which can withstand the high temperatures and can then be removed mechanically.
  • compositions of the alloy which is used for this purpose can be varied considerably it has been found that excellent results can be obtained with alloys in which the copper content may be as high as 7%.
  • the compositions which have given best results to date and are therefore the preferred compositions are those which contain about 3 to 7% copper and 0.1 to 3 titanium in lead. If the alloy is to have any wetting properties it should contain at least 0.5% copper.
  • These materials can readily be made by mixing the components and melting them in a vacuum furnace at a temperature of about 1200" C. After they have been held in the vacuum furnace for a sufficient length of time to form a homogeneous mixture they are rapidly poured into a water cooled mold. This is done in order to solidify them as rapidly as possible and thus prevent the separation of the copper V and titanium which might otherwise tend to form a more unhomogenous slug of the solidified metal.
  • An alloysuitable for the bonding'of metals'to ceramics consisting essentially of lead, titanium'and copper in which the percentage of copper lies within the range of 0.5 7%, the percentage of titanium lies within the range of .1-3% and the balance is lead.
  • An alloy suitable for the bonding of metals to ceramics consisting essentially of lead, titanium and copper in which the percentage of copper lies within the range of 0.57%, the percentage of titanium is approximately 3% andthe balance is lead,
  • the percentage of titanium lies within the range of .1 to 3 and the balance is lead.
  • An alloy suitable for the bonding of metals to ceramics consisting essentially of lead, copper, and a further metal selected from the group consisting of titanium and Zirconium, the percentage of copper being approximately 3%, the percentage of said further metal being within the range of .1 to 3%, and the balance being lead.
  • An alloy suitable for the bonding of metals to ceramics consisting essentially of lead, copper, and titanium, the percentage of copper being within the range of 3 to7%, the percentage of titanium being within the range of .l to 3% and the balance being lead.

Description

. Sept. 10,1957
H. BENDER LEAD ALLOY FOR BONDING METALS To CERAMICS Filed Sept. 16, 1953 Fig.2
lllluww A2 Fig.3
INVENTOR HARRY BEA/BBQ K ZZW United States Patent LEAD ALLQY FOR BONDENG METAES Ti) CERAhHtE Harry Bender, Alhertson, N. Y., assi'zr Electric Products Inc., a corporation of Application September 16, 1%53, Serial No. 380,533
8 Claims. (Cl. 75-466) to Sylvania ssachusetts in a gas tight manner has become more and more important and in some cases necessary for the functioning of certain electronic equipment. The simplest technique which has been developed by the prior art is the so-called silver paste technique. This technique though satisfactory for some uses does not make for a completely satisfactory gas tight bond. When the bond formed in this manner is subjected to certain types of abrasive action the metal put on in this manner has a tendency to peel off and thus destroy the gas tight seal. Many other methods have also been devised amongst them and probably one which has been considered to give the best re sults is the so-called Telefunken process in which molybdenum is used in 'promoting the metal-to-ceramic bond. When this method is used with the proper ceramics and under the right temperature conditions excellent vacuum type seals can be obtained between metal bodies and ceramics. However, the disadvantage with the process is that it must be carried out in several steps and secondly in that it is .imited in its application to the bonding of materials w..ose coefiicients of expansion are matched.
It is the object to provide an alloy for doing this which can be used successfully in the bonding together of materials whose coefiicients of expansion may be mismatched.
In accordance with this invention it has been found that these and other objects and advantages can be obtained with the use of a lead base alloy containing at least 0.5% of copper and at least 0.1% of titanium or zirconium.
in the accompanying drawings which illustrate features of this invention Figure 1 is a perspective view showing two ceramic bodies bonded together with the aid of a metal bond.
Figure 2 of the drawings is a perspective view of a .etal tube which has been metallized on one end thereof the metal extending a considerable distance up along the outside side wall.
Figure 3 is a plan view partially in section showing the alloy of this invention embedded within the pores of a screen-like material.
The alloy which has been found to be suitable for making the metal-to-ceramic seals in accordance with this invention is one which has preferably at least three component elements. The base metal is lead. Titanium or zirconium form the second component and it is present in an amount not less than 0.1%, and copper the third component is present in tin-amount not less than 0.5 With this alloy it is possible to make a good ceramic-tometal or ceramic-to-ceramic seal bonded with a metallic bond. This can be done in a single step operation and 2.8%,944 Patented Sept. 10, 1957 glass to metal or ceramic.
The alloy which is formed from the mixture of the three components is fairly ductile in nature and can be formed into bars, sheets, wire and numerous other shapes which might be deemed to be useful and adaptable in the making of the seal. A bond or seal can be made in a very simple manner, by taking the parts which are to be bonded together, subjecting them to a simple cleaning operation to remove any foreign materials which may be on the surface, placing them together, for example, to form a butt joint with a piece of the alloy material positioned therebetween, for example, in the form of a washer, and then heating them in a non-oxiding atmosphere.
To obtain best results the parts should be heated to'a temperature of 700-800 C. for a period of about three minutes. When the parts have been cooled it will be found that they have been joined in a vacuum tight manner and that the metal is tightly bonded to the ceramic and cannot be peeled or cut away from the ceramic body.
This process is very simple in nature. It requires no formidable technically detailed steps for the preparation of the material and yet results in the formation of a very good vacuum-tight bond between the materials that have been joined. Furthermore, the process can be carried out in a very simple non-oxidizing furnace in which the atmosphere is either hydrogen, vacuum or'some othe inert gas.
Figure 1 of the drawings shows two 'of ceramic parts which have been bonded together in'this manner. 10 is a tubular piece of ceramic which has been bonded to a disc-like wafer 12 by means of the alloy 14.
In Figure 2 is shown a tubular member 20 which has been metallized at one end 22 with the use of the alloy to form the metallized surface at 24. The wettability of this alloy is so good, in certain instances, when the preferred composition is made use of that there is a tendency for the alloy to run at the bond and in order to hold the alloy in place so that the metal will actually cover the areas which it is intended to mctallize it has been found that a special structure may be desirable. A structure of this type is shown in Figure 3 wherein the alloy is embedded within the pores of a screen-like material 30. There one can see the metallic parts 32 surrounding the screen-like material embedded within the interstices of the screen-like member. The member 30 is, of course, made of a metal or other material which can withstand the high temperatures and can then be removed mechanically.
Although the compositions of the alloy which is used for this purpose can be varied considerably it has been found that excellent results can be obtained with alloys in which the copper content may be as high as 7%. The compositions which have given best results to date and are therefore the preferred compositions are those which contain about 3 to 7% copper and 0.1 to 3 titanium in lead. If the alloy is to have any wetting properties it should contain at least 0.5% copper. These materials can readily be made by mixing the components and melting them in a vacuum furnace at a temperature of about 1200" C. After they have been held in the vacuum furnace for a sufficient length of time to form a homogeneous mixture they are rapidly poured into a water cooled mold. This is done in order to solidify them as rapidly as possible and thus prevent the separation of the copper V and titanium which might otherwise tend to form a more unhomogenous slug of the solidified metal.
cific details shown and described are byway of illustration and are not to be construed as limiting the scope of the invention. V
What is claimed is: 1. An alloy suitable for the bonding of metals to ceramics consisting essentially of lead containing approximately 3% titanium and 3% copper.
2. An alloysuitable for the bonding'of metals'to ceramics consisting essentially of lead, titanium'and copper in which the percentage of copper lies within the range of 0.5 7%, the percentage of titanium lies within the range of .1-3% and the balance is lead.
3. An alloy suitable for the bonding of metals to ceramics consisting essentially of lead, titanium and copper in which the percentage of copper lies within the range of 0.57%, the percentage of titanium is approximately 3% andthe balance is lead,
4. An alloy suitable for the bonding of metals to ceramics consisting essentially of lead, titanium and copper in which the percentage of copper is approximately 3%,
the percentage of titanium lies within the range of .1 to 3 and the balance is lead.
5. An alloy suitable for the bonding. of metals to ceramics consisting essentially of lead, copper, and a furth'ermetal selected from the group consisting of titanium and zirconium, the percentage of copper being Within the range of .5 to 7%, the percentage of said further metal being within the range of .1 to 3% and the balance being lead; 6. An alloy suitable for the bonding of metals to ceramics consisting essentiallyof lead, copper, and a fur- 4- ther metal selected from the and zirconium, the percentage of copper being within the range of .5 to 7%, the percentage of said further metal being approximately 3% and the balance being lead.
7. An alloy suitable for the bonding of metals to ceramics consisting essentially of lead, copper, and a further metal selected from the group consisting of titanium and Zirconium, the percentage of copper being approximately 3%, the percentage of said further metal being within the range of .1 to 3%, and the balance being lead.
8. An alloy suitable for the bonding of metals to ceramics consisting essentially of lead, copper, and titanium, the percentage of copper being within the range of 3 to7%, the percentage of titanium being within the range of .l to 3% and the balance being lead.
References Cited in the file of this patent UNITED STATES PATENTS 1,020,514 Rossi Mar. 19, 1912 1,020,516 Rossi Mar. 19, 1912 1,335,982 Petinot Apr. 6, 1920 1,500,954 Mathesius July 8, 1924 1,547,394 Hoyt July. 28, 1925 1,699,761 Silberstein July 22, 1929 2,163,408 Pulfrich June 20, 1939 2,230,205 Rowland Jan. 28, 1941 2,282,106 Underwood May 5, 1942 2,333,622 McNab Nov. 2, 1943 2,366,954 Brooks Jan. 9, 1945 2,402,661 Ohl June 25, 1946 2,454,270 Braunsdorft Nov. 23, 1948 2,461,878 Christensen Feb. 15, 1949 2,482,178 Harris Sept. 20, 1949 2,490,571 Ainceft Dec. 6, 1949 2,602,775 Isherwood July 8, 1952 2,607,981 Nelson Aug. 26, 1952 2,647,218 Sorg July. 28, 1953 group consisting of titanium

Claims (1)

1. AN ALLOY SUITABLE FOR THE BONDING OF METALS TO CERAMICS CONSISTING ESSENTIALLY OF LEAD CONTAINING APPROXIMATELY 3% TITANIUM AND 3% COPPER.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3078562A (en) * 1959-11-04 1963-02-26 Gibson Electric Company Method for attaching silver-cadmium oxide bodies to a supporting member
JPS62192295A (en) * 1986-02-19 1987-08-22 デグツサ・アクチエンゲゼルシヤフト Soft solder alloy for mutual bonding of ceramic part or bonding with part consisting of metal
US5695861A (en) * 1995-10-18 1997-12-09 Cts Corporation Solder active braze

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US1020516A (en) * 1911-01-06 1912-03-19 Titanium Alloy Mfg Co Article composed essentially of titanium and lead and method of producing the same.
US1020514A (en) * 1911-01-06 1912-03-19 Titanium Alloy Mfg Co Lead and method of purifying and improving the same.
US1335982A (en) * 1919-08-18 1920-04-06 Us Ferroalloys Corp Process for producing an alloy of zirconium and lead
US1500954A (en) * 1922-10-21 1924-07-08 Mathesius Walther Manufacture of lead alloys
US1547394A (en) * 1921-08-02 1925-07-28 Gen Electric Leading-in wire for electrical incandescent lamps and similar devices
US1699761A (en) * 1927-05-21 1929-01-22 Westinghouse Electric & Mfg Co Solder
US2163408A (en) * 1936-11-30 1939-06-20 Gen Electric Vacuum-tight seal
US2230205A (en) * 1939-10-24 1941-01-28 Locke Insulator Corp Process of connecting a metal body to a vitreous ceramic body
US2282106A (en) * 1939-07-14 1942-05-05 Gen Electric Ceramic-to-metal seal
US2333622A (en) * 1940-02-16 1943-11-02 Westinghouse Electric & Mfg Co Method of uniting dissimilar materials and the product thereof
US2366954A (en) * 1943-01-09 1945-01-09 Western Electric Co Method of making piezoelectric crystals
US2402661A (en) * 1941-03-01 1946-06-25 Bell Telephone Labor Inc Alternating current rectifier
US2454270A (en) * 1945-04-10 1948-11-23 Tung Sol Lamp Works Inc Basing electric bulb
US2461878A (en) * 1944-11-01 1949-02-15 Bell Telephone Labor Inc Metallizing composition
US2482178A (en) * 1944-02-29 1949-09-20 Western Electric Co Composite structure for forming a seal with glass
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