US2091903A - Method of treating tungsten carbide - Google Patents

Method of treating tungsten carbide Download PDF

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Publication number
US2091903A
US2091903A US48193A US4819335A US2091903A US 2091903 A US2091903 A US 2091903A US 48193 A US48193 A US 48193A US 4819335 A US4819335 A US 4819335A US 2091903 A US2091903 A US 2091903A
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Prior art keywords
tungsten carbide
charge
molten
crucible
quenching
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US48193A
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Henry T Baggett
Gorham W Woods
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Hughes Tool Co
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Hughes Tool Co
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Priority to US48193A priority Critical patent/US2091903A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/5607Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides
    • C04B35/5626Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides based on tungsten carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/51Plural diverse manufacturing apparatus including means for metal shaping or assembling
    • Y10T29/5184Casting and working

Definitions

  • Our invention relates to a method or process of making hard materials, such as tungsten carbide, employed as diamond substitutes in facing tools and the like.
  • the materials are fused in a crucible at high temperatures and are discharged from the crucible directly into a cold mold or quenching medium.
  • the resulting alloy is hard and crystalline, but is to some extent porous because of occluded air pockets therein.
  • tungsten, carbon, etc. are fused in a crucible illustrated at I. This may preferably be done by electrical means, the crucible being largely of graphite.
  • the charge When the charge is properly melted, it is poured, as shown in the drawing, into a quenching medium 2 which is preferably oil.
  • a quenching medium 2 which is preferably oil.
  • tungsten carbide thus treated is harder and of better quality than where not so compressed and quenched.
  • the porous condition of the alloy usually resulting from oldmethods is avoided.
  • the carbide in the form of thin sheets is more easily broken up and pulverized for use than is the case where it is poured into a cold mold or where it is poured directly into a quenching bath.
  • a process of forming tungsten carbide comprising bringing the ingredients thereof to a molten condition in a crucible, positioning said crucible at a point spaced above compression rolls, pouring said tungsten carbide in its molten condition in drops downwardly between the. heavy compression rolls to eliminate occluded gases, and forming the same into thin sheets and then quenching said sheets in a liquid bath.
  • a process of forming tungsten carbide comprising fusingthe charge, partly cooling the tungsten carbide in the air while pouring said charge in a molten condition between compression rolls to form the material into thin sheets and then abruptly cooling the same in a liquid quenching medium.
  • a process of forming tungsten carbide including fusing a charge of material to a molten condition, cooling the same to a semi-plastic condition, compressing the charge to eliminate occluded gases, and simultaneously forming the metal into thin sheets and then abruptly cooling said sheets.

Description

Aug. 3l, 1937. H. T. BAGGETT ET AL METHOD 0F TREATING TUNGSTEN CARBIDE Filed Nov. 4, 1935 Henry .7? 34151962? Gorkam Z0. Zdoods INVENTOR ATTORNEY Patented Aug. '31, 193
Henry T. Baggett and ton, Tex., assignors Gorham W. Woods; Housto Hughes Tool Company,
Houston, Tex, a corporation of Texas Application November 4, 1935, Serial No. 48,193
4 Claims.
Our invention relates to a method or process of making hard materials, such as tungsten carbide, employed as diamond substitutes in facing tools and the like.
In the usual method of treating tungsten carbide, the materials are fused in a crucible at high temperatures and are discharged from the crucible directly into a cold mold or quenching medium. The resulting alloy is hard and crystalline, but is to some extent porous because of occluded air pockets therein.
It is an object of our invention to subject the molten tungsten carbide to compression in its molten state so as to eliminate the air and gas. occluded therein and to prevent the porous consistency of the carbide otherwise existing.
We also desire to obtain a more rapid and thorough quenching of the alloy due to its thinner cross section where it is introduced into the oil.
In the drawing herewith is a diagrammatic view, partly in section, illustrating the application of the invention.
The proper quantities and proportions of tungsten, carbon, etc. are fused in a crucible illustrated at I. This may preferably be done by electrical means, the crucible being largely of graphite. I
When the charge is properly melted, it is poured, as shown in the drawing, into a quenching medium 2 which is preferably oil. On the pouring of the molten tungsten carbide from the crucible to the quenching medium, it is passed between two compression rolls 3 which are rotated to move the molten metal downwardly and to exert a heavy pressure thereon to eliminate all air orgas therein and to deliver the metal to the quenching tank in thin sheets which may be cooled instantly by the quenching medium.
we find that tungsten carbide thus treated is harder and of better quality than where not so compressed and quenched. The porous condition of the alloy usually resulting from oldmethods is avoided. Further, the carbide in the form of thin sheets is more easily broken up and pulverized for use than is the case where it is poured into a cold mold or where it is poured directly into a quenching bath. r
What we claim as new is:
1. A process of forming tungsten carbide comprising bringing the ingredients thereof to a molten condition in a crucible, positioning said crucible at a point spaced above compression rolls, pouring said tungsten carbide in its molten condition in drops downwardly between the. heavy compression rolls to eliminate occluded gases, and forming the same into thin sheets and then quenching said sheets in a liquid bath.
2. A process of forming tungsten carbide comprising fusingthe charge, partly cooling the tungsten carbide in the air while pouring said charge in a molten condition between compression rolls to form the material into thin sheets and then abruptly cooling the same in a liquid quenching medium.
3. A process of forming tungsten carbide including fusing a charge of material to a molten condition, cooling the same to a semi-plastic condition, compressing the charge to eliminate occluded gases, and simultaneously forming the metal into thin sheets and then abruptly cooling said sheets.
4. A process of cluding fusing -a condition, dropping the charge slowly through the air to partly cool the same, compressing the charge to eliminate occluded gases, and thenabruptly cooling the compressed carbide.
forming tungsten carbide in- HENRY T. BAGGE'IT. GORHAM W. WOODS.
charge of material to a molten
US48193A 1935-11-04 1935-11-04 Method of treating tungsten carbide Expired - Lifetime US2091903A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2631356A (en) * 1953-03-17 Method of making p-n junctions
US2683676A (en) * 1950-01-13 1954-07-13 Bell Telephone Labor Inc Production of germanium rods having longitudinal crystal boundaries
US2768914A (en) * 1951-06-29 1956-10-30 Bell Telephone Labor Inc Process for producing semiconductive crystals of uniform resistivity
US3928515A (en) * 1971-06-15 1975-12-23 Carborundum Co Semicontinuous process for producing oxide refractory material having fine crystal structure
US4202089A (en) * 1978-06-02 1980-05-13 The Singer Company Splat-cooled instrument flexure and method to fabricate same
US4276924A (en) * 1978-06-02 1981-07-07 The Singer Company Method and apparatus for casting a splat-cooled flexure member

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2631356A (en) * 1953-03-17 Method of making p-n junctions
US2683676A (en) * 1950-01-13 1954-07-13 Bell Telephone Labor Inc Production of germanium rods having longitudinal crystal boundaries
US2768914A (en) * 1951-06-29 1956-10-30 Bell Telephone Labor Inc Process for producing semiconductive crystals of uniform resistivity
US3928515A (en) * 1971-06-15 1975-12-23 Carborundum Co Semicontinuous process for producing oxide refractory material having fine crystal structure
US4202089A (en) * 1978-06-02 1980-05-13 The Singer Company Splat-cooled instrument flexure and method to fabricate same
US4276924A (en) * 1978-06-02 1981-07-07 The Singer Company Method and apparatus for casting a splat-cooled flexure member

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